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Process & contact

Member of DPP

https://terranova-energy.com/umweltschutz/
Contact:

Updated 7/3/22

Input materials

Raw or digested sludge after dewatering, from WWTPs operating biological and/or chemical P-removal.7terranova

Output products

Calcium phosphate salt according to EU 2019/1009: 
P > 8% (P2O5 > 18.3%)
Ca: 2 – 6 %
N: 1-2 % -
K < 1 %
Mg < 0.5 % 
Organic carbon 2% 
Contaminants:  
Pb < 10 mg/kg
Cr-total <50 mg/kg
Cu < 20 mg/kg
Zn < 200 mg/kg

Process description

1) continuous hydrothermal hydrolysis carbonization process at 175°C, 20-25 bars.

2) Acid treatment of hydrolysed sludge to dissolve P.

3) Mechanical separation into low-P solid “coal” and P-rich liquid filtrate.

4) Phosphate precipitation from the liquid to produce a calcium phosphate salt.

Operating status

Full scale plant operating on dewatered sewage sludge in China (since 2016) input capacity 2 t/h

Demonstration plant at Ruhrverband/Duisburg Germany, input capacity 250 kg/h.

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